The constants a and b for the pair silver-lead are 2.50 μV°C–1 and 0.012 μV°C–1 respectively. For a silver-lead thermocouple with colder junction at 0°C.
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Thermocouples are of two wire legs made from different metals. These wires legs are welded together at one end, creating a junction.
This junction is where the temperature is measured.
When the change in temperature occurs at junction, a voltage is created.
Now neutral temperature for the thermocouple.
is the temperature of the hot junction at which the thermo-emf in a thermocouple becomes maximum
For a thermocouple with constants a and b having the same sign, the neutral temperature will be less than the cold junction temperature of thermocouple, as
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Hence, there will be no neutral or inversion temperature, since the hot junction temperature cannot be less than the temperature of cold junction of thermocouple.