Which of the following graphs is correct for a zero order reaction?
for a zero-order reaction,
Rate=k[R]0
R is the molar concentration of reactants.
Hence the reaction rate remains constant with time and becomes zero when the concentration of reactants is zero.
At t=0, R=R0 and at t=t, R=R, where R is the concentration of reactants at time t.
Integrating w.r.t. t on both side and putting limit we get,
[R]=-kt + [R0]
Following an equation of a line with negative slope, hence the graph (iv) is correct.