In the following questions two or more options may be correct.
Which of the following have identical bond order?
The isoelectronic species have a similar bond order.
Both CN- and NO+ have 14 electrons.
Both CN- and NO+ have identical bond order i.e. 3.
(MOT diagram of CN-)
So, from the above diagram in CN-,
Electrons in bonding molecular orbitals = 8
Electrons in Anti Bonding Molecular orbitals = 2
Bond Order = .
= (8-2)
= 3
So, from the above MOT diagram of NO+,
Electrons in bonding molecular orbitals = 10(2e- in 1s)
Electrons in Anti Bonding Molecular orbitals = 4(2e- in 1*s)
Bond Order = .
= (10-4)
= 3.