Δf
of formation of CH4 (g) at certain temperature is –393 kJ mol–1. The value of Δf
is
Reason: C (s) + 2H2 (g) → CH4 (g)
Δf
= Δf
+ ΔngRT
Δng= 1-2= -1
Substituting the value of Δng, above equation will become
Δf
= Δf
- RT
As temperature and gas constant both have a positive value, so the value of Δf
will become more negative.