The standard molar entropy of H2O (l ) is 70 J K–1 mol–1. Will the standard molar entropy of H2O(s) be more, or less than 70 J K–1 mol–1?


o The standard molar entropy is the measure the disorderliness or randomness in per mole of a substance.


o The standard molar entropy of H2O (l ) is 70 J K–1 mol–1. The solid form of water is ice, in which position of molecules is quite fixed; therefore the disorderliness or randomness in solid molecules is less than the liquid form where the molecular orientation is more random.


Hence, entropy of H2O(s) <entropy of H2O (l ) . The standard molar entropy of H2O(s) will also be less than 70 J K–1 mol–1 .


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