Which of the following complexes show linkage isomerism?
Ambidentate ligands have more than one binding site. Both NO2 and SCN are ambidentate ligands and will therefore show linkage isomerism.
1) SCN-→ M NCS→M
Isothiocyanato Thiocyanato
2) MßNO2 MßO-N=O
Nitrito-N Nitrito-O