Calcium chloride when dissolved in water dissociates into its ions according to the following equation.
CaCl(aq) → Ca2+ (aq) + 2Cl– (aq)
Calculate the number of ions obtained from CaCl2 when 222 g of it is dissolved in water.
Molar mass of CaCl2 = The atomic mass of Ca + 2 × the atomic mass of Cl
= 40 + 35.5 × 2 = 111 g/mol
1 mole of calcium chloride = 111g
Thus, 222g of CaCl2 is equivalent to 2 moles of CaCl2
Since 1 formula unit CaCl2 gives 3 ions (one Ca2+ cation and two Cl- anions),
Therefore, 1 mole of CaCl2 will give 3 moles of ions
2 moles of CaCl2 would give 3 × 2 = 6 moles of ions.
No. of ions = No. of moles of ions × Avogadro number
= 6 × 6.022 ×1023
= 36.132 ×1023
= 3.6132 ×1024 ions