Compute the difference in masses of one mole each of aluminium atoms and one mole of its ions. (Mass of an electron is 9.1×10–28 g). Which one is heavier?
Mass of 1 mole of aluminium atom = the molar mass of aluminium = 27 g mol–1
A aluminium atom and ion, differ by three electrons. Aluminium loses three electrons to form aluminium ion.
The mass of one electron = 9.1×10–28 g
For one mole of A13+ ion, three moles of electrons are to be lost
Therefore, total number of electrons lost = 3
The mass of three moles of electrons = 3 × (9.1×10–28) × 6.022×1023 g
= 27.3 × 6.022 ×10–5 g
= 164.400 ×10–5 g
= 0.00164 g
Molar mass of Al3+ = molar mass of aluminium – mass of electrons
= 27–0.00164 = 26.9984 g mol–1
Therefore, difference in masses of one mole each of aluminium atoms and one mole of its ions
= 27 – 26.9984 = 0.0016 g