A compound forms hexagonal close-packed structure. What is the total number of voids in 0.5 mol of it? How many of these are tetrahedral voids?


Number of atoms in close packing = 0.5 mol

1 mol has 6.022x1023 particles


So that


Number of close- packed particles = 0.5 × 6.022 × 1023 = 3.011 × 1023


Number of tetrahedral voids = 2 × number of atoms in close packing plug the value we get


Number of tetrahedral voids = 2 × 3.011 × 10 23 = 6.022 × 10 23


Number of octahedral = number of atoms in close packing


So that


Number of octahedral voids = 3.011 × 10 23


Total number of voids = tetrahedral voids + octahedral voids


= 6.022 × 10 23 + 3.011 × 10 23


= 9.03 × 10 23


15
1