Predict which of the following will be coloured in aqueous solution? Ti3+, V3+, Cu+, Sc3+, Mn2+, Fe3+ and Co2+. Give reasons for each.
Metal ions which have valence electrons in d-orbital and in which d-d transition can take place will be coloured and the metal ions which have completely filled orbital or have d-orbital will be colourless as no d-d transition is possible in those configurations.
Element | Atomic Number | Ionic State | Electronic configuration in ionic state |
Ti | 22 | Ti3+ | [Ar] 3d1 |
V | 23 | V3+ | [Ar] 3d2 |
Cu | 29 | Cu+ | [Ar] 3d10 |
Sc | 21 | Sc3+ | [Ar] |
Mn | 25 | Mn2+ | [Ar] 3d5 |
Fe | 26 | Fe3+ | [Ar] 3d5 |
Co | 27 | Co2+ | [Ar] 3d7 |
From the above table, it can be observed that only Sc3+ and Cu+ have either completely filled d-orbital or empty d-orbital. So, all other ions except Sc3+ and Cu+ will be coloured in aqueous solution because of absorption of radiations which fall in the visible region as on obtaining energy electrons jump from one d-orbital to another.