(a) Write the formula of the following coordination compound : Iron(III) hexacyanoferrate (II)
(b) What type of isomerism is exhibited by the complex

(c) Write the hybridisation and number of unpaired electrons in the complex [CoF₆ ]^3- . (Atomic No. of Co = 27)

Question

(a) Write the formula of the following coordination compound : Iron(III) hexacyanoferrate (II)

(b) What type of isomerism is exhibited by the complex

(c) Write the hybridisation and number of unpaired electrons in the complex [CoF₆ ]^3- . (Atomic No. of Co = 27)

Philoid · Accepted Answer

(a) The molecular formula for coordination compound Iron(III) hexacyanoferrate(II)

Fe₄[ Fe (CN )₆]₃

(b) [Co(NH₃)₅ Cl]SO₄ will show ionisation isomerism, and the possible isomers are

[Co(NH₃)₅Cl]SO₄ and [Co(NH₃)₅ SO₄] Cl

(c) Electronic configuration of Co³⁺ ions is sp³d³ hybridized orbitals of Co³⁺, with six pairs of electrons from six F^- ions.

Hybridisation = sp ³d ³

Number of unpaired electron = 4

There are 4 unpaired electron in [CoF₆]³⁺

(a) Write the formula of the following coordination compound : Iron(III) hexacyanoferrate (II)(b) What type of isomerism is exhibited by the complex(c) Write the hybridisation and number of unpaired electrons in the complex [CoF6 ]3- . (Atomic No. of Co = 27)