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8. The d-and f-Block Elements
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Q43 of 70 Page 111

Although +3 oxidation states is the characteristic oxidation state of lanthanoidsbut cerium shows +4 oxidation state also. Why?

Ce – [Xe] 4f1 5d1 6s2. Usually lanthanoids lose the 5d and 6s electrons and show +3 oxidation state, but Cerium loses the one 4f electron also so as to attain Xenon’s noble gas configuration which will make Ce4+ very stable.


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41

Ionisation enthalpies of Ce, Pr and Nd are higher than Th, Pa and U. Why?

42

Although Zr belongs to 4d and Hf belongs to 5d transition series but it is quite difficult to separate them. Why?

44

Explain why does colour of KMnO4 disappear when oxalic acid is added to its solution in acidic medium.

45

When orange solution containing Cr2O72– ion is treated with an alkali, a yellow solution is formed and when H+ ions are added to yellow solution, an orangesolution is obtained. Explain why does this happen?

Questions · 70
8. The d-and f-Block Elements
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