Q58 of 77 Page 10

Why is FeO (s) not formed in stoichiometric composition?

Iron(II) oxide or ferrous oxide is the inorganic compound with the formula FeO. This compound also refers to a family of related non-stoichiometric compounds, which are typically iron deficient with compositions ranging from Fe0.84O to Fe0.95O. This happens because of metal deficiency defect, a non-stoichiometric defect. In crystals of FeO, some Fe2+ cations are missing and the loss of positive charge is made up by the presence of required number of Fe3+ ions. Three Fe2+ ions are replaced by two Fe3+ ions to make up for the loss of positive charge. Hence, FeO is not formed in stoichiometric composition.


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