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Q22 of 53 Page 59

At 300 K, 36 g of glucose present in a litre of its solution has a osmotic pressure of 4.98 bar. If the osmotic pressure of the solution is 1.52 bar at the same temperature, what would be its concentration?

Here,

T = 300 K


π = 1.52 bar


R = 0.083 bar L


Applying the relation, π = CRT


Where


π = osmotic pressure of solution


C = concentration of solution


R = universal gas constant


T = temperature


⇒


⇒ C = 0.061mol/L


Concentration of the solution is 0.061mol/L


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20

A 5% solution (by mass) of cane sugar in water has freezing point of 271 K. Calculate the freezing point of 5% glucose in water if freezing point of pure water is 273.15 K.

21

Two elements A and B form compounds having formula AB2 and AB4 . When dissolved in 20 g of benzene, 1 g of AB2 lowers the freezing point by 2.3 K whereas 1.0 g of AB4 lowers it by 1.3 K. The molar depression constant for benzene is 5.1K kg mol-1. Calculate atomic masses of A and B.

23

Suggest the most important type of intermolecular attractive interaction in the following pairs.

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(v) acetonitrile(CH3CN) and acetone(C3H6O)

24

Based on solute-solvent interactions, arrange the following in order of increasing solubility in n-octane and explain. Cyclohexane, KCl, CH3CN, CH3OH.

Questions · 53
2. Solutions
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