Q11 of 14 Page 333

A metre long narrow bore held horizontally (and closed at one end) contains a 76 cm long mercury thread, which traps a 15 cm column of air. What happens if the tube is held vertically with the open end at the bottom?


If the temperature is constant, then the Boyle’s law state that,


P1 V1 = P2 V2


Where,


‘P1’ is the initial pressure.


‘V1’ is the initial pressure.


‘P2’ is the final pressure.


‘V2’ is the final pressure.


Given,


The length of the tube = 1 m = 100 cm


The length of the mercury thread = 76 cm


The length of the air column = 15 cm


Therefore,


The length of 9 cm is left in the open end when the tube is kept in a horizontal position. We suppose ‘a’ cm2 as the cross section area of the tube.


When the tube is held horizontally,


Initial pressure, P1 = 76 cm (of mercury)


Initial Volume, V1 = 15 a cm3


When the tube is held vertically,



The length of the air column = 15 cm + 9 cm = 24 cm


(The two air column on the both sides of the mercury thread adds up)


The length of the mercury thread = 76 cm


(at the open end of the tube)


Since, the pressure of the mercury and the air adds up to be greater than the atmospheric pressure. Some mercury flows out of the open end until the total pressure inside reaches the atmospheric pressure.


Suppose, The length of the mercury thread that is reduced = ‘h’ cm


The length of the air column now = ( 24 + h ) cm


The length of the mercury thread now = ( 76 – h ) cm


The new final pressure, P2 = 76 cm – (76 – h ) cm


P2 = h cm ( of mercury)


The new final Volume, V2 = (24 + h) a cm3


By Boyle’s law, we have


P1V1 = P2V2


76 × 15 a = h × (24 + h) a


1140 = 24h + h2


h2 + 24h – 1140 = 0


Solving the quadratic equation we get,


cm


cm



h = 23.83 cm or h = -47.83


Since, the height cannot be negative, h = 23.83 cm


Thus, if the tube is held vertically with the open end at the bottom the mercury will flow out of the tube to equalize the pressure with the atmospheric pressure and the thread of mercury will reduce by h = 23.83 cm.


More from this chapter

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At what temperature is the root mean square speed of an atom in an argon gas cylinder equal to the rms speed of a helium gas atom at – 20 °C? (atomic mass of Ar = 39.9 u, of He = 4.0 u).

10

Estimate the mean free path and collision frequency of a nitrogen molecule in a cylinder containing nitrogen at 2.0 atm and temperature 17 °C. Take the radius of a nitrogen molecule to be roughly 1.0 Å. Compare the collision time with the time the molecule moves freely between two successive collisions (Molecular mass of N2 = 28.0 u).

12

From a certain apparatus, the diffusion rate of hydrogen has an average value of 28.7 cm3 s–1. The diffusion of another gas under the same conditions is measured to have an average rate of 7.2 cm3 s–1. Identify the gas.

13

A gas in equilibrium has uniform density and pressure throughout its volume. This is strictly true only if there are no external influences. A gas column under gravity, for example, does not have uniform density (and pressure). As you might expect, its density decreases with height. The precise dependence is given by the so-called law of atmospheres

n2 = n1 exp [ -mg (h2 h1)/ kBT]


Where n2, n1 refer to number density at heights h2 and h1 respectively. Use this relation to derive the equation for sedimentation equilibrium of a suspension in a liquid column:


n2 = n1 exp [ -mg NA(ρ - P) (h2 h1)/ (ρ RT)]


Where ρ is the density of the suspended particle, and ρ’ that of surrounding medium.


[NA is Avogadro’s number, and R the universal gas constant.]