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8. Redox reactions
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Q29 of 64 Page 272

Given the standard electrode potentials,

K+/K = –2.93V, Ag+/Ag = 0.80V,


Hg2+/Hg = 0.79V


Mg2+/Mg = –2.37V. Cr3+/Cr = –0.74V


arrange these metals in their increasing order of reducing power.

The lower the electrode potential, the stronger is the reducing agent the species is. Therefore, the increasing order of the reducing power of the given metals is Ag < Hg < Cr < Mg < K.


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26

Using the standard electrode potentials given in the Table 8.1, predict if the reaction between the following is feasible:

Br2(aq) and Fe2+(aq).

27

Predict the products of electrolysis in each of the following:

(i) An aqueous solution of AgNO3 with silver electrodes


(ii) An aqueous solution AgNO3 with platinum electrodes


(iii) A dilute solution of H2SO4 with platinum electrodes


(iv) An aqueous solution of CuCl2 with platinum electrodes.

28

Arrange the following metals in the order in which they displace each other from the solution of their salts.

Al, Cu, Fe, Mg and Zn.

30

Depict the galvanic cell in which the reaction Zn(s) + 2Ag+(aq) → Zn2+(aq) +2Ag(s) takes place, Further show:

(i) which of the electrode is negatively charged,


(ii) the carriers of the current in the cell, and


(iii) individual reaction at each electrode.

Questions · 64
8. Redox reactions
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