Q13 of 18 Page 226

Represent each of the following molecules using Lewis notation:

(a) bromine gas (Br2)


(b) Calcium chloride (CaCl2)


(c) carbon dioxide (CO2)


(d) Which of the three molecules listed above contains a double bond?

(a)


Bromine is a halogen element. It has 7 electrons in its outermost orbit. It needs one more electron to obtain octet and become stable. Hence, in the case of bromine gas, 2 bromine atoms combine to form a molecule (Br2). Each bromine atom contributes one electron for covalent bond. So, the 2 electrons involved in the bond are shared by both bromine atoms, hence octet is obtained.


(b)


Calcium has 2 electrons in outermost shell. It tends to lose them to get octet structure. Chlorine being halogen element has 7 electrons in the outermost orbit. It needs one more electron to obtain octet and become stable. So, calcium donates its 2 electrons to 2 different chlorine atoms. Hence, calcium cation, chlorine anions are formed and bond forms.


Thus, CaCl2 is formed.


(c)


Oxygen has 6 electrons in its outermost orbit. Carbon has 4 electrons in its outermost orbit. So, oxygen tends to gain 2 electrons to obtain octet. Carbon shares electrons to obtain octet. So, in this case, one carbon and 2 oxygen atoms share electrons. Each oxygen contributes its 2 electrons and carbon contributes 4 electrons. 2 pairs of electrons between each oxygen and carbon form bonds. These electrons are shared by both oxygen and carbon. Both carbon and oxygen obtain octet. Thus, 2 double bonds are formed and CO2 is formed.


(d) Carbon dioxide –


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