Q7 of 11 Page 88

2 kg of water at 293 K is converted completely into ice at 273 K. Calculate the heat liberated.

Given:

Temperature = 293 K


Mass of water = 2kg


To convert water in liquid form to solid form.


Formula used:


Q = mc(ΔT)


Q = mF


where m is the mass (Kg)


F is the latent heat of fusion of ice (J/kg)


c is the specific heat of water (J/kg-K)


ΔT is the temperature difference(K)


Step 1


Heat liberated in conversion from water at 293K to water 273K


ΔT = Initial temperature (of water) – Final temperature (of ice)


= 293K – 273K


= 20K


Q = mc(ΔT)


Q1 = 2 kg × 4.2×103 J/kg-K × (20K)


= 168 × 103 J


STEP 2


Heat liberated in conversion of water from liquid state to solid state.


Q = mF


Q2 = 2 Kg × 336 × 103 J/kg


= 672 × 103 J


The water diagram is shown here:



Total heat released = Sum of Q1 + Q2 = 810 × 103 J


Ans = 810 × 103 J


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