2 kg of water at 293 K is converted completely into ice at 273 K. Calculate the heat liberated.
Given:
Temperature = 293 K
Mass of water = 2kg
To convert water in liquid form to solid form.
Formula used:
Q = mc(ΔT)
Q = mF
where m is the mass (Kg)
F is the latent heat of fusion of ice (J/kg)
c is the specific heat of water (J/kg-K)
ΔT is the temperature difference(K)
Step 1
Heat liberated in conversion from water at 293K to water 273K
ΔT = Initial temperature (of water) – Final temperature (of ice)
= 293K – 273K
= 20K
Q = mc(ΔT)
⇒ Q1 = 2 kg × 4.2×103 J/kg-K × (20K)
= 168 × 103 J
STEP 2
Heat liberated in conversion of water from liquid state to solid state.
Q = mF
⇒ Q2 = 2 Kg × 336 × 103 J/kg
= 672 × 103 J
The water diagram is shown here:

Total heat released = Sum of Q1 + Q2 = 810 × 103 J
Ans = 810 × 103 J
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