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13. Amines
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Q55 of 77 Page 188

Complete the following reaction.


Benzene diazonium chloride reacts with phenol under mild basic condition to form p-hydroxyazobenzene as the major product. This type of reaction is known as coupling reaction. P- hydroxyazobenzene are often coloured and are used as orange dyes.


The chemical reaction involved in this case is:



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53

A compound Z with molecular formula C3H9N reacts with C6H5SO2Cl to give a solid, insoluble in alkali. Identify Z.

54

A primary amine, RNH2 can be reacted with CH3—X to get secondary amine, R—NHCH3 but the only disadvantage is that 3° amine and quaternary ammonium salts are also obtained as side products. Can you suggest a method where RNH2 forms only 2° amine?

56

Why is aniline soluble in aqueous HCl?

57

Suggest a route by which the following conversion can be accomplished.


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13. Amines
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