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13. Amines
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Q56 of 77 Page 188

Why is aniline soluble in aqueous HCl?

We know that aniline is a colourless liquid and is sparingly soluble in water.


Aniline reacts with aqueous HCl to form Anilinium chloride. Anilinium chloride is soluble in water. Thus, aniline is soluble in aqueous HCl.


The chemical reaction involved in this case is:



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54

A primary amine, RNH2 can be reacted with CH3—X to get secondary amine, R—NHCH3 but the only disadvantage is that 3° amine and quaternary ammonium salts are also obtained as side products. Can you suggest a method where RNH2 forms only 2° amine?

55

Complete the following reaction.


57

Suggest a route by which the following conversion can be accomplished.


58

Identify A and B in the following reaction.


Questions · 77
13. Amines
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