Q2 of 30 Page 188

When hydrochloric acid is added to the cobalt nitrate solution at room temperature, the following reaction takes place :


The solution is blue at room temperature. However, it turns pink when cooled in a freezing mixture. Based on this information, which of the following expression is correct for the forward reaction?


Enthalpy is a thermodynamic quantity equivalent to the total heat content of a system. It is equal to the internal energy of the system plus the product of pressure and volume.


Since the reaction shifts to backward direction on cooling, this means that the backward reaction is an exothermic reaction. Therefore, the forward reaction is an endothermic reaction and ∆H > 0. On the other hand, enthalpy cannot be zero(C option) because this above-given process is not isothermal(constant temperature).

More from this chapter

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1

The pressure-volume work for an ideal gas can be calculated by using the expression;


The work can also be calculated from the pV plot by using the area under the curve within the specified limit. When an ideal gas is compressed reversibly or irreversibly from volume Vi to Vf, which of the following is correct?


3

Which of the following elements does not form hydride by direct heating with dihydrogen?

4

Which of the following species should be aromatic in character?

5

Identify the pairs which are of isotopes?