Give the characteristic tests for the following gases
(a) CO2
(b) SO2
(c) O2
(d) H2
(a) When carbon dioxide is made to run through lime water, the gas turns the solution milky. This is unique only to carbon dioxide.
The reaction produces Calcium carbonate which is a white precipitate, thus giving rise to the milky appearance. Lime water is nothing but a solution of Calcium hydroxide.
CO2 + H2O → H2CO3
H2CO3 + Ca(OH)2→ CaCO3 + 2H2O
(b) The unique identifying feature of sulphur dioxide is its odour.It smells like burning of sulphur. Also, Sulphur dioxide turns moist litmus paper from blue to red.
When SO2 is passed through acidified potassium permanganate solution (pink/purple in colour) , the solution turns green due to the formation of Chromium sulphate. It is a redox reaction where Potassium dichromate acts as an oxidising agent and sulphur dioxide acts as a reducing agent.
Cr2O72- (aq) + 2H+ (aq) + 3SO2 (g) → 2Cr3+ (aq) + H2O (l) + 3SO42- (aq)
(c) When any fire element - a matchstick or a candle - is brought into an oxygen atmosphere, it starts burning more brightly.
Oxygen supports combustion.
(d) When a fire element - a matchstick or a candle - is brought into a Hydrogen atmosphere, it burns with a pop sound. This is unique to Hydrogen.
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