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1. The Solid State
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Q18 of 68 Page 21

An element with molar mass 2.7×10-2 kg mol-1 forms a cubic unit cell with edge length 405 pm. If its density is 2.7×103 kg m-3, what is the nature of the cubic unit cell?

Given information:-

Molar mass of the element = 2.7×10-2 kg mol-1


Edge length, a = 405 pm


Density, d = 2.7×103 kg m-3


Using the formula, d


Putting the values given at their appropriate place, we get



= 3.99 which is approximately equal to 4


Therefore, it is an fcc unit cell.


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16

A compound is formed by two elements M and N. The element N forms ccp and atoms of M occupy 1/3rd of tetrahedral voids. What is the formula of the compound?

17

Which of the following lattices has the highest packing efficiency

(i) simple cubic


(ii) body-centred cubic and


(iii) Hexagonal close-packed lattice?

19

What type of defect can arise when a solid is heated? Which physical property is affected by it and in what way?

20

What type of stoichiometric defect is shown by?

(i) ZnS (ii) AgBr

Questions · 68
1. The Solid State
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