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3. Electrochemistry
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Q8 of 33 Page 83

Suggest a way to determine the Λ°m value of water

Λ°m (H2O) = Λ°m(H+) + Λ°m(OH-)


For calculation purpose, Λ°m(Na+) and Λ°m(Cl-) are added and subtracted.


Λ°m (H2O) = Λ°m(H+) + Λ°m(OH-)+ Λ°m(Na+) - Λ°m(Na+) + Λ°m(Cl-) - Λ°m(Cl-)


Λ°m (H2O) = Λ°m(HCl) + Λ°m(NaOH) - Λ°m(NaCl)


If we know the other values, Λ°m (H2O) can be calculated.


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6

The Cell in which the following reaction occurs:

2Fe3+(aq) + 2I– (aq) → 2Fe2+(aq) + I2(s) has E0cell = 0.236V at 298 K.


Calculate the standard Gibbs energy and the equilibrium constant of the cell reaction.

7

Why does the conductivity of a solution decrease with dilution?

9

The molar conductivity of 0.025 mol L–1 methanoic acid is 46.1 S cm2 mol–1. Calculate its degree of dissociation and dissociation constant. Given λ0(H+) = 349.6 S cm2 mol–1 and λ0 (HCOO–) = 54.6 S cm2 mol–1.

10

If a current of 0.5 ampere flows through a metallic wire for 2 hours, then how many electrons would flow through the wire?

Questions · 33
3. Electrochemistry
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