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4. Chemical Kinetics
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Q24 of 39 Page 117

Consider a certain reaction A → Products with k = 2.0 × 10–2s-1. Calculate the concentration of A remaining after 100 s if the initial concentration of A is 1.0 mol L–1.

Given,


k = 2.0 × 10–2s-1


time t = 100s


Concentration [A0] = 1.0 mol L-1


We know,


On substituting the values,


Log(1/[A]) = 2.303/2


Log[A] = -2.303/2


[A] = 0.135 mol L–1


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22

The rate constant for the decomposition of N2O5 at various temperatures is given below:



















T/°C



0



20



40



60



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0.0787



1.70



25.7



178



2140



Draw a graph between ln k and 1/T and calculate the values of A and Ea. Predict the rate constant at 30° and 50°C.

23

The rate constant for the decomposition of hydrocarbons is 2.418 × 10–5s–1 at 546 K. If the energy of activation is 179.9 kJ/mol, what will be the value of pre-exponential factor.

25

Sucrose decomposes in acid solution into glucose and fructose according to the first order rate law, with t1/2 = 3.00 hours. What fraction of sample of sucrose remains after 8 hours?

26

The decomposition of hydrocarbon follows the equation

k = (4.5 × 1011s–1) e-28000K/T. Calculate Ea.

Questions · 39
4. Chemical Kinetics
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