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Blind - 2016
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Q18 of 26 Page 1

Write down the structural formula of the organic compounds A, B and C in the following sequence of reactions:


A = CH3CH(Br)CH3 (addition is done according to Markonikov’s rule)


B = CH3CH(OH)CH3 (Br is replaced by OH)


C = CH3CH(Cl)CH3 (OH is replaced by Cl)


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16

Account for the following:

(i) Transition metals form coloured compounds.


(ii) Actinoids show wide range of oxidation states.


(iii) Zinc has lowest enthalpy of atomization in 3d series.


OR


What must be the stable oxidation states of the transition elements with the following configuration in the ground state of their atoms: 3d3, 3d5, 3d8, 3d4


17

Write the hybridization, magnetic character and shape of [Fe(CN)6]3- [Atomic Number of Fe=26]

(ii) Write down IUPAC name of [Co(NH3)5NO2] (NO3)2.


19

Write the reactions of Phenol with:

(i) Br2 water (ii) dil. HNO3 (iii) Zn dust


20

(a) Give chemical tests to distinguish between the following pairs of compounds.

(i) (CH3)2NH and (CH3)3N


(ii) Aniline and Ethylamine


(b) Write IUPAC name of CH3CH2NHCH3.


Questions · 26
Blind - 2016
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26
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