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Foreign - 2016
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Q13 of 26 Page 1

An element crystallizes in a fcc lattice with cell edge of 400 pm. Calculate the density if 200 g of this element contain 2.5 × 1024 atoms.

Given,


Edge length, a = 400 pm = 400 m


Z = 4 (fcc lattice)


6.022 1023 atoms are present in 1 mole of element.


2.5 × 1024 atoms are present in 200 g of element.


6.022 1023 atoms are present in g/mol.


Therefore, M = 48.16 g/mol


Substituting values in d =


d=


d = 4.99 106 g/m3


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11

For the first order thermal decomposition reaction, following data were obtained:


Calculate the rate constant.


(Given: log 2 = 0.301, log 3 = 0.4771, log 4 = 0.6021)


12

Give reasons:

(i) The -hydrogen atoms of aldehydes and ketones are acidic in nature.


(ii) Propanone is less reactive than ethanol toward addition of HCN.


(iii) Benzoic acid does not give Friedal-Crafts reaction.


OR


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(ii) Ethanoic acid to 2-chloroethanoic acid


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14

Define the following terms:

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(ii) Zeta potential


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15

Calculate the freezing point of solution when 2 g of Na2SO4 (M = 142 gmol-1) was dissolved in 50 g of water, assuming Na2SO4 undergoes complete ionization. (Kf for water = 1.86 K kg mol-1)

Questions · 26
Foreign - 2016
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