Q7 of 40 Page 1

When chromite ore is fused with NaOH in presence of air, a yellow coloured compound (A) is obtained which on acidification with dilute sulphuric acid gives a compound (B). Compound (B) on reaction with KCl forms a orange coloured crystalline compound (C).

A. Write the formulae of the compounds (A), (B) and (C)


B. Write one use of compound (C).

When FeCr2O4 is fused with NaOH in presence of air, the resultant is Sodium Chromate (Na2CrO4):

4FeCr2O4 + 16NaOH +7O28Na2CrO4 + 2Fe2O3 + 8H2O


Hence A = Na2CrO4


Sodium Chromate upon acidification with dilute sulphuric acid gives sodium dichromate:


2Na2CrO4 + H2SO4Na2Cr2O7 + Na2SO4 +H2O


Hence B = Na2Cr2O7


Sodium Dichromate reacts with potassium chloride (KCl) to give potassium dichromate which an orange coloured crystalline compound:


Na2Cr2O7 + 2KCl K2Cr2O7 + 2NaCl


Hence C = Na2Cr2O7


Potassium Dichromate is used as a precursor to potassium chrome alum and also used in leather tanning. It is also used as an oxidizing agent.


More from this chapter

All 40 →