When chromite ore
is fused with NaOH in presence of air, a yellow coloured compound (A) is obtained which on acidification with dilute sulphuric acid gives a compound (B). Compound (B) on reaction with KCl forms a orange coloured crystalline compound (C).
A. Write the formulae of the compounds (A), (B) and (C)
B. Write one use of compound (C).
When FeCr2O4 is fused with NaOH in presence of air, the resultant is Sodium Chromate (Na2CrO4):
4FeCr2O4 + 16NaOH +7O2→8Na2CrO4 + 2Fe2O3 + 8H2O
Hence A = Na2CrO4
Sodium Chromate upon acidification with dilute sulphuric acid gives sodium dichromate:
2Na2CrO4 + H2SO4→Na2Cr2O7 + Na2SO4 +H2O
Hence B = Na2Cr2O7
Sodium Dichromate reacts with potassium chloride (KCl) to give potassium dichromate which an orange coloured crystalline compound:
Na2Cr2O7 + 2KCl→ K2Cr2O7 + 2NaCl
Hence C = Na2Cr2O7
Potassium Dichromate is used as a precursor to potassium chrome alum and also used in leather tanning. It is also used as an oxidizing agent.
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