The silver jewellery becomes dull after prolonged use. Explain
Silver jewellery when exposed to air for a long time causes silver to react with the sulphur present in the air. A coating of silver sulphide is formed over the jewellery thus making it appear dull and black.
Black coating on silver jewellery:
2Ag + H2S (present in air) → Ag2S + H2
The black coating is of Ag2S. The chemical name is silver sulphide.
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