Q13 of 33 Page 225

Organic compound ‘A’ of molecular formula C2H6O liberates hydrogen gas with sodium metal. ‘A’ gives ‘B’ of formula C4H10O, when it reacts with concentrated H2SO4 at 413K. At 443K with concentrated H2SO4 ‘A’ gives compound ‘C’ of formula C2H4. This compound ‘C’ decolourises bromine water. What are ‘A’, ‘B’ and ‘C’?

It is given that organic compound liberates hydrogen gas with sodium metal.


i. It must be an ethanol. Ethanol reacts with sodium metal to form sodium ethoxide and hydrogen gas.



ii. When ethanol (A) reacts with concentrated H2SO4 at 413K, it gives diethylether (B).



iii. When ethanol (A) reacts with concentrated H2SO4 at 413K, it gives ethene (C)



Ethene (C) when reacts with bromine water, it delcolourises it.


Thus, A is ethanol.


B is diethyl ether.


C is ethene.


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