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10. Haloalkanes and Haloarenes
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Q53 of 97 Page 142

Draw other resonance structures related to the following structure and find out whether the functional group present in the molecule is ortho, para directing or meta directing.


The other resonance structures are as follows:


The functional group present in these molecules are ortho-para directing as electron density is more at ortho and para positions.


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51

Which of the products will be major product in the reaction given below?

Explain.


CH3CH=CH2 + HI → CH3CH2CH2I + CH3CHICH3


(A) (B)


52

Why is the solubility of haloalkanes in water very low?

54

Classify the following compounds as primary, secondary and tertiary halides.

(i) 1-Bromobut-2-ene


(ii) 4-Bromopent-2-ene


(iii) 2-Bromo-2-methylpropane


55

Compound ‘A’ with molecular formula C4H9Br is treated with aq. KOH solution. The rate of this reaction depends upon the concentration of the compound ‘A’ only. When another optically active isomer ‘B’ of this compound was treated with aq. KOH solution, the rate of reaction was found to be dependent on concentration of compound and KOH both.

(i) Write down the structural formula of both compounds ‘A’ and ‘B’.


(ii) Out of these two compounds, which one will be converted to the product with inverted configuration?


Questions · 97
10. Haloalkanes and Haloarenes
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