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Chemistry
10. Haloalkanes and Haloarenes
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Q75 of 97 Page 142

Predict the major product formed when HCl is added to isobutylene. Explain the mechanism involved.

The reaction of HCl and isobutylene is given as:


The mechanism of the reaction is given as follows:



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73

Aryl halides are extremely less reactive towards nucleophilic substitution. Predict and explain the order of reactivity of the following compounds towards nucleophilic substitution from arylhalides?

(I)



(II)



(III)



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tert-Butylbromide reacts with aq. NaOH by SN1 mechanism while n-butylbromide reacts by SN2 mechanism. Why?

76

Discuss the nature of C–X bond in the haloarenes.

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Questions · 97
10. Haloalkanes and Haloarenes
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