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Set-I
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Q5 of 22 Page 1

What is the formula of a compound in which the element Y forms ccp lattice and atoms of X occupy 2/3 rd of tetrahedral voids?

Since, Y forms ccp lattice, the no. of atoms of Y =


= 4


No. of tetrahedral voids in lattice = 2 (no. of atoms of Y)


= 2


Since, X occupy 2/3rd of tetrahedral voids, then no. of atoms of Y = 8 =


Formula of compound =


= X4Y3


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4

Which would undergo SN1 reaction faster in the following pair:

?


6

Write one similarity and one difference between the chemistry of lanthanoids and that of actinoids.

7

(i) Write down the IUPAC name of the following complex: [Co(NH3)5Cl] 2+

(ii) Write the formula for the following complex: Potassium tetrachloridonickelate(II)


8

Write the reagents required in the following reactions:

(i) CH2 = CH − CH2OH ¾ CH2 = CH − CHO


(ii) CH3− COOH ¾ CH3− CONH2


OR


Arrange the following compounds in increasing order of their property as indicated:


(i) CH3COCH3, C6H5COCH3, CH3CHO (reactivity towards nucleophilic addition reaction)


(ii) Cl − CH2− COOH, F − CH2− COOH, CH3 − COOH (acidic character)


Questions · 22
Set-I
4 5 6 7 8 9 10 11 12 13 14 16 17 18 19 20 21 22 23 24 25 26
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