AP and AQ are two tangents drawn from an external point A to a circle with centre O, P and Q are points of contact. If PR is a diameter, let us prove that OA ∥ RQ

In Δ APO and Δ AQO
AP = AQ (Tangents drawn to the same circle from an external point are always equal in length)
AO = AO (Common)
∠ OPA = ∠ OQA (Tangents are perpendicular to the line joining the centre)
So Δ APO and Δ AQO are congruent by S.A.S. axiom of congruency.
So from corresponding parts of congruent triangle we get
∠ POA = ∠ QOA = x (Let)
∠ POA + ∠ QOA = 2x
∠ QOR = 1800-2x (Angle on a straight line)
∠ OQR = ∠ ORQ (Δ OQR is isosceles)
∠ OQR + ∠ ORQ = 1800-(1800-2x) = 2x
Since they are equal so
∠ OQR = x = ∠ AOQ
∠ OQR and ∠ AOQ forms a pair of alternate interior angles
So OA∥ RQ
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