SF6 is known but SCl6 is not. Why?
fluorine is strongest oxidizing agent and it can oxidize sulphur to its maximum oxidation state +6 to form SF6. Chlorine is not good oxidizing agent, it cannot oxidize sulphur to its maximum oxidation state. Chlorine can oxidize sulphur to only +4 oxidation state. Hence it can form SCl4 but not SCl6.
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