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7. The p-block Elements
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Q46 of 72 Page 96

SF6 is known but SCl6 is not. Why?

fluorine is strongest oxidizing agent and it can oxidize sulphur to its maximum oxidation state +6 to form SF6. Chlorine is not good oxidizing agent, it cannot oxidize sulphur to its maximum oxidation state. Chlorine can oxidize sulphur to only +4 oxidation state. Hence it can form SCl4 but not SCl6.


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44

Give reason to explain why ClF3 exists but FCl3 does not exist.

45

Out of H2O and H2S, which one has higher bond angle and why?

47

On reaction with Cl2, phosphorus forms two types of halides ‘A’ and ‘B’. Halide A is yellowish-white powder but halide ‘B’ is colourless oily liquid. Identify A and B and write the formulas of their hydrolysis products.

48

In the ring test of NO3– ion, Fe2+ ion reduces nitrate ion to nitric oxide, which

combines with Fe2+ (aq) ion to form brown complex. Write the reactions involved in the formation of brown ring.


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7. The p-block Elements
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