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Chemistry
7. The p-block Elements
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Q48 of 72 Page 96

In the ring test of NO3– ion, Fe2+ ion reduces nitrate ion to nitric oxide, which

combines with Fe2+ (aq) ion to form brown complex. Write the reactions involved in the formation of brown ring.


+ 3Fe2+ + 4H+ NO + 3Fe2+ 2H2O


[Fe(H2O)6]SO4 + NO [Fe(H2O)5NO]SO4


Thus the complex formed is brown in colour.


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46

SF6 is known but SCl6 is not. Why?

47

On reaction with Cl2, phosphorus forms two types of halides ‘A’ and ‘B’. Halide A is yellowish-white powder but halide ‘B’ is colourless oily liquid. Identify A and B and write the formulas of their hydrolysis products.

49

Explain why the stability of oxoacids of chlorine increases in the order given below:

HClO< HClO2< HClO3< HClO4


50

Explain why ozone is thermodynamically less stable than oxygen.

Questions · 72
7. The p-block Elements
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