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7. The p-block Elements
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Q54 of 72 Page 96

Nitric acid forms an oxide of nitrogen on reaction with P4O10. Write the reaction involved. Also write the resonating structures of the oxide of nitrogen formed.

P4O10 + 4HNO3 4HPO3 + 2N2O5

White phosphorous is very reactive as compared to red phosphorous due to angular strain in white phosphorous.


Resonance structure of N2O5


dowghh.jpg


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52

White phosphorus reacts with chlorine and the product hydrolyses in the presence of water. Calculate the mass of HCl obtained by the hydrolysis of the product formed by the reaction of 62 g of white phosphorus with chlorine in the presence of water.

53

Name three oxoacids of nitrogen. Write the disproportionation reaction of that oxoacid of nitrogen in which nitrogen is in +3 oxidation state.

55

Phosphorus has three allotropic forms — (i) white phosphorus (ii) red phosphorus and (iii) black phosphorus. Write the difference between white and red phosphorus on the basis of their structure and reactivity.

56

Give an example to show the effect of concentration of nitric acid on theformation of oxidation product.

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7. The p-block Elements
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