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7. The p-block Elements
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Q58 of 72 Page 96

Phosphorus forms a number of oxoacids. Out of these oxoacidsphosphinicacid has strong reducing property. Write its structure and also write a reaction showing its reducing behaviour.

REACTIONS SHOWING REDUCING BEHAVIOR:

4AgNO3 + H3PO2 + 2H2O 4Ag + H3PO4 + 4HNO3


2HgCl2 + H3PO2 + 2H2O 2Hg + H3PO4 + 4HCl




It shows reducing behavior due to possession of P-H bond


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56

Give an example to show the effect of concentration of nitric acid on theformation of oxidation product.

57

PCl5 reacts with finely divided silver on heating and a white silver salt is obtained, which dissolves on adding excess aqueous NH3 solution. Write the reactions involved to explain what happens.

59

Match the compounds given in Column I with the hybridisation and shape given in Column II and mark the correct option.

Code :


60

Match the formulas of oxides given in Column I with the type of oxide given in Column II and mark the correct option.

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7. The p-block Elements
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