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7. The p-block Elements
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Q56 of 72 Page 96

Give an example to show the effect of concentration of nitric acid on theformation of oxidation product.

dilute and concentrated nitric acid give different oxidation product

EXAMPLES ARE:


4Zn +10HNO3(dil) 4Zn(NO3)2 + NH4NO3 + 3H2O


4Zn +10HNO3(dil) 4Zn(NO3)2 + N2O + 5H2O


4Zn +4HNO3(conc.) Zn(NO3)2 + NO2 + 2H2O


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54

Nitric acid forms an oxide of nitrogen on reaction with P4O10. Write the reaction involved. Also write the resonating structures of the oxide of nitrogen formed.

55

Phosphorus has three allotropic forms — (i) white phosphorus (ii) red phosphorus and (iii) black phosphorus. Write the difference between white and red phosphorus on the basis of their structure and reactivity.

57

PCl5 reacts with finely divided silver on heating and a white silver salt is obtained, which dissolves on adding excess aqueous NH3 solution. Write the reactions involved to explain what happens.

58

Phosphorus forms a number of oxoacids. Out of these oxoacidsphosphinicacid has strong reducing property. Write its structure and also write a reaction showing its reducing behaviour.

Questions · 72
7. The p-block Elements
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