Q13 of 71 Page 418

The product of the hole concentration and the conduction electron concentration turns out to be independent of the amount of any impurity doped. The concentration of conduction electrons in germanium is 6 × 1019 per cubic meter. When some phosphorus impurity is doped into a germanium sample, the concentration of conduction electrons increases to 2 × 1023 per cubic meter. Find the concentration of the holes in the doped germanium.


Given:


Initially,


Concentration of conduction electron


Concentration of holes


After doping,


Concentration of conduction electron


Concentration of holes


We know,


Product of concentration of conduction electron and that of holes remains constant,




number of holes after doping


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11

The conductivity of a pure semiconductor is roughly proportional to T3/2 e–ΔE/2kT where ΔE is the band gap. The band gap for germanium is 0.74 eV at 4 K and 0.67 eV at 300 K. By what factor does the conductivity of pure germanium increase as the temperature is raised from 4 K to 300 K.

12

Estimate the proportion of boron impurity which will increase the conductivity of a pure silicon sample by a factor of 100. Assume that each boron atom creates a hole and the concentration of holes in pure silicon at the same temperature is 7 × 1015 holes per cubic meter. Density of silicon is 5 × 1028 atoms per cubic meter.

14

The conductivity of an intrinsic semiconductor depends on temperature as σ = σ0 e–ΔE/2kT, where σ0 is a constant. Find the temperature at which the conductivity of an intrinsic germanium semiconductor will be double of its value at T = 300 K. Assume that the gap for germanium is 0.650 eV and remains constant as the temperature is increased.

15

A semiconducting material has a band gap of 1 eV. Acceptor impurities are doped into it which create acceptor levels 1 meV above the valence band. Assumed that the transition from one energy level to the other is almost forbidden if kT is less than 1/50 of the energy gap. Also, if kT is more than twice the gap, the upper levels have maximum population. The temperature of the semiconductor is increased from 0K. The concentration of the holes increase with temperature and after a certain temperature it becomes approximately constant. As the temperature is further increased, the hole concentration again starts increasing at a certain temperature. Find the order of the temperature range in which the hole concentration remains approximately constant.