Diatomic molecules like hydrogen have energies due to both translational as well as rotational motion. From the equation in kinetic theory Pv =
E , E is
In kinetic theory, ideal gas is treated as point masses. Point masses do not have rotational or vibrational motion. During collision we assume walls exert only perpendicular force on molecules and not parallel force, hence there will not be any rotation. The wall produce only change in translational motion.
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