Q27 of 30 Page 1

Differentiate between thermoplastic and thermosetting polymers. Give one example of each.

Thermoplastics and thermosetting polymers are two separate classes of polymers, which are differentiated based on their behaviour in the presence of heat.


• The basic difference lies that between the two thermoplastics can be re-melted (its shape can be altered by heating it again and again), while thermoset polymers remain in a permanent solid state once hardened (shape cannot be altered by heating it).


So we get to know that thermoplastics are soft and weak and can be bent easily into shapes. So they are used in making toys.


• Thermosetting polymers cannot be bent easily as they are hard and strong. They are used in making handles of cooking utensils.


• Polyacrylonitrile(PAN) or Acrilan is a thermoplastic (which becomes soft when heated and hard when cooled and can be moulded into shapes) hard material having high melting point. It is prepared by polymerization of acrylonitrile. Its another commercial name is Orlon .



Bakelite is a thermoplastic. As a result they are poor conductors of electricity and subsequently they are highly heat resistant. So they are used in switches to prevent us from getting electrical shocks.


Novolac is prepared from phenol(C6H5OH) and formaldehyde(HCHO). It is thus known as phenol-formaldehyde resin commonly as Bakelite.



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Answer the following questions :
(i) What is meant by chirality of a compound? Give an example.
(ii)Which one of the following compounds is more easily hydrolyzed by KOH and why?
CH3CHClCH2CH3 or CH3CH2CH2Cl

(iii) Which one undergoes SN2substitution reaction faster and why?




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What is essentially the difference between α-glucose and β-glucose? What is meant by pyranose structure of glucose?

28

(a) Define the following terms :
(i) Mole fraction.
(ii) Ideal solution.
(b) 15.0 g of an unknown molecular material was dissolved in 450 g of water. The resulting solution was found to freeze at -0.34 °C. What is the molar mass of this material? (Kƒ for water = 1.86 K kg mol-1 )
OR
(a) Explain the following:
(i) Henry’s law about dissolution of a gas in a liquid.
(ii) Boiling point elevation constant for a solvent.
(b) A solution of glycerol (C3H8O3) in water was prepared by dissolving some glycerol in 500 g of water. This solution has a boiling point of 100.42°C. What mass of glycerol was dissolved to make this solution? (KA for water = 0.512 K kg mol-1).

29

(a) Draw the molecular structures of the following compounds:
(i) N2O5
(ii)XeOF4.
(b) Explain the following observations:
(i) Sulphur has a greater tendency for catenation than oxygen.
(ii)I-Cl is more reactive than I2.
(iii)Despite lower value of its electron gain enthalpy with negative sign, fluorine (F2) is a stronger oxidizing agent than Cl2.
OR
(a) Complete the following chemical equations:
cbse-previous-year-solved-papers-class-12-chemistry-outside-delhi-2012-22
(b)Explain the following observations :
(i)Phosphorus has greater tendency for catenation than nitrogen.
(ii)Oxygen is a gas but sulphur a solid.
(iii)The halogens are coloured. Why?