Q7 of 79 Page 3

By what chemical processes do you obtain the following metals?
i) Mercury from HgO  ii) Iron from Fe2O3  iii) Manganese from MnO2  iv) Sodium form NaCl  v) Aluminium from Al2O3.

i) Mercury from mercuric oxide can be obtained by simple heating.
2HgO 2Hg + O2 ii) Iron from iron oxide (Fe2O3) can be obtained by carbon reduction method i.e heating with coke.
2C + O2   2CO
Fe2O3 + 3CO   2Fe + 3CO2 iii) Manganese from manganese dioxide is obtained by alumino thermite process, i.e. heating with aluminium.
3MnO2 + 4Al   2Al2O3 + 3Mniv) Sodium from sodium chloride is obtained by electrolytic reduction (electrolysis) of fused NaCl.
NaCl   Na+ + Cl-
At anode  2Cl-   Cl2 + 2e-
At cathode 2[Na= +e-   Na]
v) Al2O3   2 Al3+ + 3(O)2-
At cathode 4[2Al3+ + 6e   2Al]
At anode 6O2-   3O2 + 12e-.

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