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10. Haloalkanes and Haloarenes
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Q8 of 102 Page 310

What are ambident nucleophiles? Explain with an example.

Ambident Nucleophiles are those nucleophilies which can attack through different sites.


For example:-cyanide ions are a resonance hybrid of the following two structures:



It can attack through carbon to form cyanide and through N to form is O cyanide.


Example: NO2, NO3- etc.


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7

Write the equations for the preparation of 1-iodobutane from

1-chlorobutane

7

Write the equations for the preparation of 1-iodobutane from

but-1-ene.

9

Which compound in each of the following pairs will react faster in SN2 reaction with –OH?

(i) CH3Br or CH3I (ii) (CH3)3CCl or CH3Cl

10

Predict all the alkenes that would be formed by dehydrohalogenation of the following halides with sodium ethoxide in ethanol and identify the major alkene:

1-Bromo-1-methylcyclohexane

Questions · 102
10. Haloalkanes and Haloarenes
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