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10. Haloalkanes and Haloarenes
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Q15 of 102 Page 310

Write the mechanism of the following reaction:

nBuBr + KCN nBuCN

The given reaction is a nucleophillic reaction:


nBuBr + KCN nBuCN


The given reaction is an SN2 reaction. In this reaction, CN acts as the stronger nucleophile and attacks the carbon atom to which Br is attached in nBuBr.


And, CN- ion is an ambident nucleophile and can attack through both C and N. In this case, it attacks through the C-atom.


The mechanism is shown below:



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Write the structure of the major organic product in each of the following reactions:

CH3CH2CH = CH2+ HBr

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Write the structure of the major organic product in each of the following reactions:

CH3CH = C(CH3)2 + HBr

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Arrange the compounds of each set in order of reactivity towards SN2 displacement:

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Arrange the compounds of each set in order of reactivity towards SN2 displacement:

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Questions · 102
10. Haloalkanes and Haloarenes
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