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10. Haloalkanes and Haloarenes
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Q11 of 102 Page 310

How will you bring about the following conversions?

Ethane to bromoethene

The bromination of ethane (Br2 in the presence of light at 520-670K) gives bromoethane which on further treatment with alcoholic KOH results in the alkene called ethane which again on bromination with Br2/CCl4 gives dibromide(vicinal bromide) called 1,2-dibromoethane which on treatment with alcoholic KOH gives bromoethene as the final product.



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10

Predict all the alkenes that would be formed by dehydrohalogenation of the following halides with sodium ethoxide in ethanol and identify the major alkene:

2,2,3-Trimethyl-3-bromopentane.

11

How will you bring about the following conversions?

Ethanol to but-1-yne

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Propene to 1-nitropropane

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10. Haloalkanes and Haloarenes
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