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10. Haloalkanes and Haloarenes
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Q19 of 102 Page 310

How the following conversions can be carried out?

tert-Butyl bromide to isobutyl bromide

It is an antimarkovnikoff reaction in which under presence of a peroxide an alkene undergoes substitution, wherein the halo group is attached to that carbon which has least no. Of alkyl groups attached to it.


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The treatment of alkyl chlorides with aqueous KOH leads to the formation of alcohols but in the presence of alcoholic KOH, alkenes are major products. Explain.

Questions · 102
10. Haloalkanes and Haloarenes
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