In the rhombus ABCD, the length of the side AB is 4 cm. and ∠BCD = 60°. Let us write the length of the diagonal BD.

Let us make a diagram from given information as above,
As, ABCD is a rhombus and all sides of a rhombus are equal
AB = BC = CD = DA = 4 cm
Now, In ΔBCD
BC = CD [sides of rhombus are equal]
∠CBD = ∠CDB [Angles opposite to equal sides are equal]
In ΔBCD
∠CBD + ∠CDB + ∠BCD = 180°
⇒ ∠CBD + ∠CBD + 60° = 180°
⇒ 2∠CBD = 120°
⇒ ∠CBD = 60°
So, we have ∠CBD = ∠CDB = ∠BCD = 60°
As, all angles are 60°, ΔBCD is an equilateral triangle
∴ BC = CD = BD [All sides of an equilateral triangle are equal]
⇒ BD = 4 cm
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