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Chemistry
All India - 2014
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Q18 of 53 Page 1

Write the name of monomers used for getting the following polymers:
(i) Bakelite
(ii) Neoprene

(i) Monomers of Bakelite are Phenol & Formaldehyde
(ii) Monomer of Neoprene is 2-chloro–1,3–butadiene (or Chloroprene)


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16

Write the equations involved in the following reactions:
(i) Reimer – Tiemann reaction
(ii) Williamson synthesis

17

Write the mechanism of the following reaction:


19

(a) Calculate ΔrG0 for the reaction:

Mg(s) + Cu2+ (aq) → Mg2+(aq) + Cu(s)


(Given: E0cell = +2.71V, 1F = 96500 C/mol)


(b) Name the type of cell which was used in Apollo space programme for providing electrical power.


20

The following data were obtained during the first order thermal decomposition of SO2Cl2 at a constant volume:

SO2Cl2(g) → SO2(g) + Cl2(g)


Experiment Time/ s-1 Total pressure/atm


1 0 0.4


2 100 0.7


Calculate the rate constant.


(Given: log 4 = 0.6021, log 2 =0.3010)


Questions · 53
All India - 2014
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