Q21 of 55 Page 1

The following data were obtained during the first order thermal decomposition of at a constant volume



Calculate the rate constant.


(Given: Log4 = 0.6021 and Log2 = 0.3010)


The thermal decomposition of at a constant volume is represented by the following equation.




At t = 0 0 0


At t = t pp


After time, t, total pressure,





Therefore,




For a first order reaction,




At t = 100 s








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