The following data were obtained during the first order thermal decomposition of
at a constant volume
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Calculate the rate constant.
(Given: Log4 = 0.6021 and Log2 = 0.3010)
The thermal decomposition of
at a constant volume is represented by the following equation.
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At t = 0
0 0
At t = t
pp
After time, t, total pressure,
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Therefore,
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For a first order reaction,


At t = 100 s




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